Re: rozkład termiczny wody

Autor: krzysztof kleszcz <k.kleszcz_at_gmail.com>
Data: Fri 25 Mar 2011 - 11:23:20 MET
Message-ID: <AANLkTimuT6w1jntJGCdS=VOnQkRmzuCn8NmpzNS=7Jg8@mail.gmail.com>
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Chyba się wyjasniło. Poniżej cytat z
Applied Catalysis B: Environmental 47 (2004) 47–58

"Catalytic combustion of hydrogen for mitigating hydrogen risk
in case of a severe accident in a nuclear power plant: study of
catalysts poisoning in a representative atmosphere"
Franck Morfin, Jean-Christophe Sabroux, Albert Renouprez

"Nevertheless, overheating of the reactor core above
1200 C in the presence of steam can induce a runaway
oxidation of the zircaloy (an alloy of zirconium and tin)
composing the fuel cladding. The 29,660 kg of zircaloy
present in the pressure vessel of a French 1400MWe PWR
could yield a mean 18.2% H2 in a dry atmosphere [5]. Indeed,
a large amount of energy is produced by this exothermic
oxidation, raising the temperature and resulting in a
self-acceleration of the in-vessel core melt down:

Zr + 2H2O(vap) → ZrO2 + 2H2,
dH = −617 kJ/mol

Up to 15,000m3 STP of hydrogen can be released within
a few hours during this critical step, including the destruction
of the core support structure and control rods, creating,
together with the melted fuel rods, the so-called corium
slumping down into the lower head of the pressure vessel"

W skrócie - następuje zniszczenie struktury prętów paliwowych i
wymieszanie całego tego bajzlu, więc założenie o dostępności tylko Zr
z powierzchni było błędne. To chyba wyjaśnia sprawę.
Pozdrawiam,
kk
Received on Fri Mar 25 11:23:25 2011

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